1) The speed constant for the second order reaction in the gas phase
It varies with the temperature according to the table below. Calculate the activation energy for the process, according to Arhhenius' equation

1) The Speed Constant For The Second Order Reaction In The Gas PhaseIt Varies With The Temperature According

Answers

Answer 1

Answer:

41.7 kJ/mol

Explanation:

ln(k) = ln(A) − Eₐ/(RT)

Pick any two points.  I'll choose 100°C and 400°C.

When T = 100°C = 373 K, k = 1.10×10⁻⁹ L/mol s:

ln(1.10×10⁻⁹) = ln(A) − Eₐ/(R × 373)

When T = 400°C = 673 K, k = 4.40×10⁻⁷ L/mol s:

ln(4.40×10⁻⁷) = ln(A) − Eₐ/(R × 673)

Subtract the two equations and solve:

ln(4.40×10⁻⁷) −  ln(1.10×10⁻⁹) = -Eₐ/(R × 673) + Eₐ/(R × 373)

5.991 = 0.00120 Eₐ/R

Eₐ/R = 5013.4

Eₐ = 41700 J/mol

Eₐ = 41.7 kJ/mol


Related Questions

Someone please help me pass gen chem....

Suppose a boil water notice is sent out advising all residents in the area to boil their water before drinking it or using it for cooking. You need to boil 16.5 L of water using your natural gas (primarily methane) stove. What volume of natural gas is needed to boil the water if only 17.9% of the heat generated goes towards heating the water. Assume the density of methane is 0.668 g/L, the density of water is 1.00 g/mL, and that the water has an initial temperature of 20.4 °C. Enthalpy of formation values can be found in this table. Assume that gaseous water is formed in the combustion of methane.​

Answers

Answer:

Solution-

From the question the volume of water = 18 L = 18000 mL

Now we can find the mass of water = (volume of water) * (density of water)

mass of water = (18000 mL) * (1.00 g/mL)

mass of water = 18000 g

Now we find the heat required to boil water = (mass of water) * (specific heat water) * (final temperature - initial temperature)

putting the value the heat required to boil water = (18000 g) * (4.184 J/g.oC) * (100 oC - 22.7 oC)

heat required to boil water = 5821617.6 J

heat required to boil water = 5821.62 kJ

The heat given by the combustion = (heat required to boil water) / (percent of heat taken by boiling)

Heat given by combustion = (5821.62 kJ) / (19.4 /100)

Therefore the heat given by combustion = (5821.62 kJ) / (0.194)

Heat given by combustion = 30008.35 kJ

As we know that the enthalpy of combustion of methane = 802.5 kJ/mol

The moles methane used = (Heat given by combustion) / (enthalpy of combustion of methane)

moles methane used = (30008.35 kJ) / (802.5 kJ/mol)

So the moles methane used = 37.39 mol

Now the mass methane = (moles methane used) * (molar mass methane)

The mass methane = (37.39 mol) * (16.04 g/mol)

The mass methane = 599.74 g

Now the volume methane = (mass methane) / (density of methane)

volume methane = (599.7356 g) / (0.660 g/L)

volume methane = 908.69 L

hope helped!!

plz mark brainliest:DD

The volume of natural gas needed to boil the water if only 17.9% of the heat is generated towards heating water is ; 918.70 L

Using the given data :

Volume of water = 16.5 L = 16500 mL

mass of water = 16500 g  ( 16500 mL * 1.00 g/mL )

Density of methane = 0.668 g/L

Density of water = 1.00 g/mL

First step : determine the heat needed to boil the water

Heat required = mass of water * specific heat water * ( Δ T )

                        = 16500 * 4.184 * ( 100 - 20.4 ) =  5495265.6 J

                        = 5495.265 kJ

∴ Heat required to boil water = 5495.265 kJ

next step ; determine the heat given by combustion

heat given by combustion = ( Heat required to boil water) / ( % of heat generated )

Heat given by combustion = ( 5495.265 ) / ( 17.9 % )

                                             = 30699.80 kJ

Enthalpy of methane combustion = 802.5 kJ/mol

∴ moles of methane used = ( 30699.80 ) / ( 802.5 ) = 38.26 mol

next ; determine the mass of methane ( natural gas )

= ( moles of methane used ) * ( molar mass )

= 38.26 * 16.04 g/mol = 613.69 g

Final step : Calculate the volume of natural gas is needed to boil the water

= mass of natural gas / density of methane

= 613.69 g / 0.668 g/L

= 918.70 L

Hence we can conclude that the volume of natural gas needed to boil water if only 17.9% of the heat is  918.70 L .

Learn more : https://brainly.com/question/24212060

How are salinity, temperature and circulation related?

Answers

Answer:

Salinity, along with temperature, determines the density of seawater, and hence its vertical flow patterns in thermohaline circulation. 2. Salinity records the physical processes affecting a water mass when it was last at the surface. Hope this helps!

Explanation:

help me please loves

Answers

Answer:

K and ba

Explanation:

Answer: K and Ba

Explanation:

The image below shows a model of the atom. Which subatomic particle does the arrow in
the image below identify?
?
A. electron
B. neutron
C. orbital
D. proton

Answers

The correct answer is A. Electron

Explanation:

The model of this atom depicts the nucleus of this in the center of the model, this section of the atom contains sub-particles known as protons and neutrons. Moreover, in the atom, the nucleus is surrounded by three sub-particles that orbit or move around the nucleus. These sub-particles are the electrons; these differ from other sub-particles because they have a negative charge and they are not part of the nucleus. Also, these move around the nucleus is orbits, although they move similarly to waves. According to this, the correct answer is A.

Determine the value of the equilibrium constant (report your answer to three significant figures) for the following reaction if an equilibrium mixture contains 0.010 mol of solid PbBr2, and is 0.0100 M in Pb2+ ions and 0.0250 M in Br1- ions. Use the notation 4.31e-5 to indicate a number such as 4.31 x 10-5.

Answers

Answer:

6.25e-6 is the value of the equilibrium constant

Explanation:

we have this equation

[tex]PbBr(s) ----- Pb^{2+}(aq) + 2Br(aq)[/tex]

When at a state of equilibrium,

we have the concentration of Pb^2+ to be 0.01

we have the concentration of Br^- to be 0.025

the equilibrium constant concentration of both pure solids and liquid s are said to be equal to 1

[PbBR2] = 1

such tht

Keq = [Pb^2+] x [Br-]^2

we already know the values of these from the above.

0.01x0.025^2

= 0.01 x 0.000625

= 0.00000625

= 6.25 x 10^-6

= 6.25e^-6

Please help me ! Thank you

Answers

Answer:

10

Explanation:

Answer:
10
Explanation:

3 letters start from X​

Answers

Answer:

xanthophyll

xenobiotic

xenon

X group

x-rays

x-ray tube

Methanol has a density of 0.79g/ml: Calculate the mass of 589ml of methanol.

Answers

Answer:

The answer is 465.31 g

Explanation:

The mass of a substance when given the density and volume can be found by using the formula

mass = Density × volume

From the question we have

mass = 0.79 × 589

We have the final answer as

465.31 g

Hope this helps you

What was the atomic theory about?

A. The properties of the nucleus
B. The existence of isotopes
C. The structure of the atom
D. The existence of electrons

Answers

Answer:

The structure of the atom

Do you think there’s an advantage of process 1 over process 2 for this species?

Answers

Answer:

witch one witch species witch bone of 1 and 2

Answer:

Yes, process 1 has an advantage over process 2 for the planarian worm. Process 1 requires only one parent. If the planarian can’t find a mate, the life cycle will continue because it can still reproduce.

Explanation:

i did it

Suppose you are studying the kinetics of the iodine-catalyzed decomposition of hydrogen peroxide. 2 H 2 O 2 ⟶ 2 H 2 O + O 2 If you determine the initial rate is 7.50 × 10 − 4 M/s when [ H 2 O 2 ] = 0.546 M and [ K I ] = 0.212 M , what is the rate constant? Assume that the order of both reactants is 1.

Answers

Answer:

[tex]k=6.48x10^{-3}M^{-1}s^{-1}[/tex]

Explanation:

Hello.

In this case, based on the given information, we can write the rate law as shown below:

[tex]r=k[H_2O_2][KI][/tex]

Since the overall order of reaction is 2 being 1 for reach reactant. Thus, by knowing the initial rate and concentrations, the rate constant turns out:

[tex]k=\frac{r}{[H_2O_2][KI]}=\frac{7.50x10^{-4}M/s}{0.546M*0.212M}\\ \\k=6.48x10^{-3}M^{-1}s^{-1}[/tex]

Best regards!

The rate constant, k is [tex]6.48x10^{-3}M^{-1}s^{-1}[/tex]

Rate law:

The rate law should be

[tex]r = k[H_2O_2]{KI}[/tex]

Since the total order of the reaction is 2 being 1 for reach reactant. So, by knowing the beginning rate and concentrations, the rate constant turns out:

[tex]k = \frac{r}{k[H_2O_2]{KI}} = \frac{7.50x10^{-4}M/s}{0.546M\times 0.212M}[/tex]

k = [tex]6.48x10^{-3}M^{-1}s^{-1}[/tex]

Learn more about reactants here; https://brainly.com/question/21029530

what particular distribution you share in earth?​

Answers

Answer:

trees

Explanation:

we plant trees hindi sure kung tama to hihi

80.20%, 11.01 amu
19.80%, 10.81 amu
What is the Average Atomic Mass?

Answers

(0.8020 x 11.01) + (0.1980 x 10.81) = 10.97.

Therefore, the average atomic mass units is 10.97

What is the molarity of a solution that contains 7.0 moles of solute in 9.0 liters of solution?

Answers

Answer:

The answer is 0.78 mol/dm³

Explanation:

In order to calculate the molarity of the solution we use the formula

[tex]c = \frac{n}{v} \\ [/tex]

where

c is the molarity

n is the number of moles

v is the volume in dm³

From the question

n = 7 mol

v = 9 L = 9 dm³

We have

[tex]c = \frac{7}{9} \\ = 0.77777777...[/tex]

We have the final answer as

0.78 mol/dm³

Hope this helps you

Write the letter of the correct term for each definition in the blank. Use each term only once.

a. filtration
b. distillation
c. decantation
d. evaporation
e. centrifugation
f. chromatography

1. Separates substances on the basis of the boiling points of the substances:__________
2. Separates solutions based on boiling points when one substance remains a solid:__________
3. Separates pure substances from a mixture based upon different rates of flow:__________
4. Separates solids from liquids by pouring the liquid off the top of the solid:__________
5. Separates solids from liquids by using a porous barrier:__________
6. Separates heterogeneous substances based upon different densities:__________

Answers

Answer:

1.b. distillation

2.d. evaporation

3.f. chromatography

4.c. decantation

5.a. filtration

6.e. centrifugation

Explanation:

1. Distillation is the process in which a homogenous mixture of liquid is separated on the basis of difference in boiling points of the substances.

2. Evaporation is the process in which water is converted into gas or vapor based on the boiling point of water or solid.

3. Chromatography is defined as the process used to pure substances from a mixture based on the flow rate of the fluid. The fluid mixture to be separated is called the mobile phase that flows on a stationary phase.

4. Decantation is defined as the process that separates mixtures in which water is poured off the substance to be separated or over solid.

5. Filtration is a separation process in which solids can be separated from liquids by pouring the mixture over a porous barrier.

6. Centrifugation is defined as the separation process that separates heterogeneous substances on the basis of densities in which centripetal acceleration allows substance with high density to move outward in the radial direction.

what are the benefits of using supercritical fluids in EGS​

Answers

Answer:

See detailed explanation.

Explanation:

Hello.

In this case, it is firstly necessary to cite that EGS accounts enhanced geothermal systems which are man-made reservoirs, placed where lots of  hot rock is present but there is lack natural permeability, which requires a fluid to be injected into the subsurface to re-open it and therefore creating permeability.

Typically, water has been used for this purpose, but due to the current issue on saving water alternative methods such as supercritical fluids has been being implemented because they have better dynamic properties such as lower viscosities and therefore larger flow velocities, supercritical CO2 is easy and cheap to get as low temperatures are required to turn it in supercritical condition.

Best regards.!

The most reactive metal is one with
O 4 valence electrons
1 valence electron
O 2 valence electrons
o 3 valence electrons
Help me!

Answers

1 valence electron

Explanation:

It is because the metal having one valence electron can readily lose single electron from its outermost shell.

Answer: the answer is 1 valence electron

Explanation: just did a test with this quest thx for the points good luck :D

3. A student took a calibrated 200.0 gram mass, weighed it on a laboratory balance, and
found it read 196.5 9. What was the student's percent error?

Answers

Answer:

The answer is 1.71 %

Explanation:

The percentage error of a certain measurement can be found by using the formula

[tex]P(\%) = \frac{error}{actual \: \: number} \times 100\% \\ [/tex]

From the question

actual mass = 200 g

error = 200 - 196.59 = 3.41

We have

[tex]p(\%) = \frac{3.41}{200} \times 100 \\ = 1.705[/tex]

We have the final answer as

1.71 %

Hope this helps you

Which is the dependent variable in an experiment? 1.what I observe. 2. what I keep the same 3.What I change in the experiment. HELP NOW​

Answers

Answer:

1.what I observe.

Explanation:

The dependent variable in an experiment is what is being observed in the experimental procedure.

This variable is the one that is closely tied to the effects originating from changing the independent variables.

Independent variables are the ones that cause the observation being studied. The effects produced and then studied are the dependent variables.

Which statement describes how this rock was likely formed?
slow cooling of magma beneath the surface of Earth
rapid cooling of magma beneath the surface of Earth
slow cooling of lava on the surface of Earth
rapid cooling of lava on the surface of Earth

I will mark Brainlyest

Answers

Answer:

A

Explanation:

Slow cooling of magma beneath the surface of earth

To solve this we must be knowing each and every concept related to rock and its formation. Therefore, the correct option is option A among all the given options.

What is rock?

Rock is a naturally occurring mineral aggregate that is cohesive and composed of one or even more minerals. These aggregates often take the shape of recognisable and mappable volumes and are the fundamental building block of the solid Earth.

Mineral crystals as well as the sorts of rocks that serve as their hosts cycle through many forms as geologic materials. Temperature, weight, time, and variations in the climate in the Earth's crust and on its surface all play a role in the process. Slow cooling of magma beneath the surface of Earth is the  statement that best describes the formation of rock.

Therefore, the correct option is option A.

To learn more about rock, here:

https://brainly.com/question/29767269

#SPJ2

Which 2 letters have the most kinetic energy?

W

X

Y

Z

Answers

Answer:

See Explanation (X and Z)

Explanation:

The question has missing details as the attachment that illustrates the graph is missing.

I'll answer this question using the attached.

Kinetic energy increases as height decreases

Base on the attachment, from order of highest height to the least, we have:

W

Y

Z

X

So, we can conclude that X has the highest kinetic energy and it is immediately followed by Z

Hence:

X and Z answers the question

A student reacts 5.0 g of sodium with 10.0 g of chlorine and collect 5.24 g of sodium chloride. What is the percent yield of this combination reaction

Answers

Answer: The percent yield of this combination reaction is 41.3 %

Explanation : Given,

Mass of [tex]Na[/tex] = 5.0 g

Mass of [tex]Cl_2[/tex] = 10.0 g

Molar mass of [tex]Na[/tex] = 23 g/mol

Molar mass of [tex]Cl_2[/tex] = 71 g/mol

First we have to calculate the moles of [tex]Na[/tex] and [tex]Cl_2[/tex].

[tex]\text{Moles of }Na=\frac{\text{Given mass }Na}{\text{Molar mass }Na}[/tex]

[tex]\text{Moles of }Na=\frac{5.0g}{23g/mol}=0.217mol[/tex]

and,

[tex]\text{Moles of }Cl_2=\frac{\text{Given mass }Cl_2}{\text{Molar mass }Cl_2}[/tex]

[tex]\text{Moles of }Cl_2=\frac{10.0g}{71g/mol}=0.141mol[/tex]

Now we have to calculate the limiting and excess reagent.

The balanced chemical equation will be:

[tex]2Na+Cl_2\rightarrow 2NaCl[/tex]

From the balanced reaction we conclude that

As, 2 mole of [tex]Na[/tex] react with 1 mole of [tex]Cl_2[/tex]

So, 0.217 moles of [tex]Na[/tex] react with [tex]\frac{0.217}{2}=0.108[/tex] moles of [tex]Cl_2[/tex]

From this we conclude that, [tex]Cl_2[/tex] is an excess reagent because the given moles are greater than the required moles and [tex]Na[/tex] is a limiting reagent and it limits the formation of product.

Now we have to calculate the moles of [tex]NaCl[/tex]

From the reaction, we conclude that

As, 2 mole of [tex]Na[/tex] react to give 2 mole of [tex]NaCl[/tex]

So, 0.217 mole of [tex]HCl[/tex] react to give 0.217 mole of [tex]NaCl[/tex]

Now we have to calculate the mass of [tex]NaCl[/tex]

[tex]\text{ Mass of }NaCl=\text{ Moles of }NaCl\times \text{ Molar mass of }NaCl[/tex]

Molar mass of [tex]NaCl[/tex] = 58.5 g/mole

[tex]\text{ Mass of }NaCl=(0.217moles)\times (58.5g/mole)=12.7g[/tex]

Now we have to calculate the percent yield of this reaction.

Percent yield = [tex]\frac{\text{Actual yield}}{\text{Theoretical yield}}\times 100[/tex]

Actual yield = 5.24 g

Theoretical yield = 12.7 g

Percent yield = [tex]\frac{5.24g}{12.7g}\times 100[/tex]

Percent yield = 41.3 %

Therefore, the percent yield of this combination reaction is 41.3 %

Choose all the right answers.
Choose the two places where continental glaciers can be seen.
Iceland
Norway
Antarctica
Greenland

Answers

Antarctica and Greenland

Answer:

the real answer is Iceland, Norway, Antarctica.

Explanation:

It is not Green land proof Glaciers are not an unusual sight in Greenland due to the gigantic ice sheet that covers most of the country. However, there are only a few places where the glaciers occur immediately adjacent to a town, and therefore can be appreciated on an excursion.  

proof for Antarctica These large-scale features of glacial erosion can be seen in Antarctica where rock protrudes above the surface of the ice sheet There are many glaciers in the Antarctic. ... The lists include outlet glaciers, valley glaciers, cirque glaciers, tidewater glaciers and ice streams. Ice streams are a type of glacier and many of them have "glacier" in their name, e.g. Pine Island Glacier

proof for Norway are the largest glaciers on mainland Norway. ... In total, Norway has around 1,600 glaciers - 900 of these are in North Norway, but 60% of the total glacier area is south of Trøndelag. 1% of mainland Norway is covered by glaciers.

proof for Iceland Glaciers in Iceland are among the best natural wonders in the world. In fact, the country's glaciers are so great that you can see them from space! With 11% of the total land area covered by ice caps, Iceland is a glacier paradise. Here are the five most amazing glaciers that you must see when visiting Iceland!

(5x10^3) + (4.3x10^4)=

Answers

Answer:

48000

Explanation:

maths

Answer:

48000

Explanation:

(5x10^3) = 5 × 1000 = 5000

(4.3x10^4) = 4.3 × 10000 = 43000

5000 + 43000 = 48000

Zinc wire is added to an iron(II) nitrate solution.
Express your answer as a chemical equation. Identify all of the phases in your answer. Enter noreaction if there is no reaction.

Answers

Answer:

Zn(s) + Fe(NO₃)₂(aq) ⇒ Zn(NO₃)₂(aq) + Fe(s)

Explanation:

When metal zinc is added to an iron (II) nitrate solution, we can see the following redox reaction:

Zn(s) + Fe(NO₃)₂(aq) ⇒ Zn(NO₃)₂(aq) + Fe(s)

Zinc is oxidized since its oxidation number increases from 0 to +2.

Iron is reduced since its oxidation number decreases from +2 to 0.

a compound has a molecular formular of C12H24O6.What is the compound's empirical formula ​

Answers

Answer:

The empirical formula for C12 H24 O6 is C2 H4 O.

Answer:

We are given the formula of the compound:

C12H24O6

The empirical formula of a molecular formula is the lowest whole number ratio between the number of atoms of each element

The ratio of C to H to O in the given formula is :

12 : 24 : 6

we notice that all 3 of the numbers have 6 in common. Dividing all three of the numbers by 6, we get:

2 : 4 : 1

Hence, the ratio of Carbon to Hydrogen to Oxygen in the empirical formula of the given compound is 2 : 4 : 1 ,

Empirical Formula = C2H4O

The discharge of chromate ions (CrO42-) to sewers or natural waters is of concern because of both its ecological impacts and its effects on human health if the receiving water is later used as a drinking water source. One way in which chromate can be removed from solution is by its reaction with ferrous ions (Fe2+) to form a mixture of chromic hydroxide and ferric hydroxide solids [Cr(OH)3(s) and Fe(OH)3(s), respectively], which can then be filtered out of the water. The overall reaction can be represented as
CrO42- + 3 Fe2+ + 8 H2O --> Cr(OH)3(s) + 3 Fe(OH)3(s) + 4 H+
How much particulate matter would be generated daily by this process at a facility that treats 60 m3/h of a waste stream containing 4.0 mg/L Cr, if the treatment reduces the Cr concentration enough to meet a discharge limit of 0.1 mg/L?

Answers

Answer:

45727g

Explanation:

So, have the overall ionic equation given as the following;

CrO42^- + 3 Fe2^+ + 8 H2O ------> Cr(OH)^3(s) + 3 Fe(OH)^3(s) + 4 H^+.

So, we have (from the question) that the amount or quantity of the waste stream daily = 60m^3/h, and the waste stream daily contains waste stream containing = 4.0 mg/L Cr, and the discharge limit = 0.1 mg/L.

Step one: convert m^3/ h to L/h. Therefore, 60 m^3/h × 1000dm^3 = 60000 L/h .

Step two: Determine or calculate the the value of Cr used up.

The value of Car used up ={ 60,000 × ( 4.0 - 0.1) } ÷ 1000 = 234 g.

Step three: Determine or calculate the mass of Cr(OH)3 and the mass of Fe(OH)3.

The number of moles of Cr = 234/52 = 4.5 moles.

Molar mass of Cr(OH)3 = 103 g/mol and the molar mass of Fe(OH)3 = 106.8 g/mol.

Thus, the mass of Cr(OH)3 = 4.5 × 103 = 463.5 g.

And the mass of Fe(OH)3 = 13.5 × 106.8 = 1441.8 g.

Hence, the total = 463.5 g + 1441.8 g = 1905.3 g.

Step four: Determine or calculate the How much particulate matter would be generated daily.

The amount of the particulate that would be generated daily = 24 × 1905.3 = 45727g.

1. Determine the electron-domain geometry and molecular geometry for each of the following.

a. SBr2
b. PI4+
c. IBr2−

2. The following three compounds all have the same general formula, XF4. Compare the electron-domain geometries of these three compounds and explain what characteristic(s) of the central atom causes differences in geometry.

a. SiF4:
b. SeF4:
c. XeF4:

Answers

Answer:

SBr2: Electron geometry-tetrahedral; molecular geometry-trigonal pyramidal

PI4+: Electron geometry-tetrahedral; molecular geometry-tetrahedral

IBr2−: Electron geometry- Trigonal bipyramidal ; molecular geometry- linear

Explanation:

In SBr2, the molecule is of the structure type AX2E2 hence it is based on a tetrahedron but have two lone pairs of electrons hence the molecular geometry is trigonal pyramidal.

PI4+ has four electron domains and all of them are bond pairs hence both electron geometry and molecular geometry are both tetrahedral.

IBr2- is of the structure type AX2E3 hence it is based on a trigonal bipyramd and has a linear molecular geometry.

2)

SiF4 has a tetrahedral molecular and electron domain geometry because the central atom(Si) has no lone pairs.

SeF4 has a trigonal bipyramidal electron geometry with the structure AX4E. Its molecular geometry is See-saw since it has one lone pair of electrons that causes a deviation from its ideal trigonal bypyramidal geometry.

XeF4 has  an octahedral electron domain geometry and the molecule is AX4E2. The two lone pairs are positioned above and below the plane of a square hence the molecule is square planar.

iron (III) oxide pentahydrate formula

Answers

Answer:

Molecular Formula Fe2O12S3·5H2O

IUPAC Name iron(3+);tri sulfate;pentahydrate

Explanation:

Reactions are classified as either exothermic or endothermic. . ____________ reactions feel hot (e.g., a burning campfire), whereas _________reactions feel cool.

Answers

Answer:

Exothermic reactions feel hot

Endothermic reactions feel cool

Explanation:

In an exothermic reaction, heat is given out by the system. The energy of the reactants is greater than that of the products hence the excess energy is given off as heat. The reaction vessel feels hot.

In an endothermic reaction, the energy of products is greater than that of the reactants hence energy is taken into the system and the reaction vessel feels cool.

Other Questions
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